Vienna is the capital of Austria, and is also one of the nine states of Austria. Vienna is Austria's primary city; with a population of about 1.7 million (2.3 million within the metropolitan area), it is by far the largest city in Austria as well as its cultural, economic, and political center. It is the 10th largest city by population in the European Union and was listed by Mercer Human Resource Consulting as having the 2nd highest quality of living (as of 2008).

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Vienna is host to many major international organizations such as the United Nations and OPEC. Vienna lies in the very east of Austria and is close to the Czech Republic, Slovakia and Hungary. In 2001, the city centre was designated a UNESCO World Heritage Site and in 2005 an Economist Intelligence Unit study of 127 world cities ranked it first equal with Vancouver for the quality of life.

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Brussels, officially the Brussels Capital-Region, is the capital city of the European Union (EU) and the largest urban area in Belgium. It should not be confused with the much smaller City of Brussels (founded circa 580) within it, which is the capital of Belgium (and Flanders) by law.

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Brussels has grown from a 10th-century fortress town founded by Charlemagne's grandson into a metropolis of more than one million inhabitants. After the end of World War II, Brussels has been an important centre for international politics. It hosts the main institutions of the European Union, and the headquarters of the North Atlantic Treaty Organization (NATO). Thus, Brussels is the polyglot home of many international organisations, diplomats and civil servants. Brussels is the EU's third-richest city in terms of per capita income.

Sofia listen is the capital and largest city of the Republic of Bulgaria, with a population of 1,346,665 in the Capital Municipality. It is located in western Bulgaria, at the foot of the mountain massif Vitosha, and is the administrative, cultural, economic, and educational centre of the country.

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One of the oldest cities in Europe, the history of Serdica-Sredets-Sofia can be traced back some 7000 years; prehistoric settlements were excavated in the centre of the present city, near the royal palace, as well as in outer districts such as Slatina and Obelia. The well preserved town walls (especially their substructures) from antiquity date back before the 7th century BC, when Thracians established their city next to the most important and highly respected mineral spring, still functioning today.